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Calcium
Pantothenate
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Calcium
Pantothenate is one of the B group of vitamins and is present in
nearly all winemaking ingredients. Rarely it may be deficient to
such an extent as to cause a stuck ferment. However, as there is
usually enough present in the must and starter to prevent this, it
is not considered essential as an additive. Its action is that of
an enzyme in the reaction which oxidizes pyruvic acid to
acetaldehyde.
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Calcium
Sulphate
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Calibrated
Jars
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Calibrated
Jars are useful pieces of equipment for measuring fruit juices at
pressing time. Measurement is important both with regard to yield
of juice and also for working out necessary dilutions to achieve
the proper balance in the must.
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Candida
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Candida
A genus of yeasts called imperfecta due to the fact that they are
incapable of forming spores. There are many species, varying from
those which cause Thrush in man to wine spoilage organisms.
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Candida
Albicans
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Candida
Albicans The type of species Candida (it is the main species and
all others are identified by reference to it). This is the species
responsible for the condition known as Thrush; it is, however, not
a wine spoilage organism.
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Candida
Mycoderma
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Candida
Mycoderma The species of Candida of greatest importance to the
winemaker. It is a film yeast and its most commonly seen as a grayish-green scum or skin on the surface of the lees in the
bottom of unwashed bottles. It is an aerobic organism and forms a
pellicle or skin on the surface of the wine. At the same time it
converts the alcohol to carbon dioxide and water. Infection starts
as small whitish patches on the surface of the wine which
gradually increase in size and join together to form the pellicle.
Prevention is by hygiene and anaerobic conditions. Cure is to
sulphite the wine heavily and break up the pellicle. After a few
days, the particles sink to the bottom of the container and the
wine can be racked off.
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Candy
Sugar
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Candy
Sugar is an expensive way of buying pure sugar, since granulated
sugar is also pure. Many recipes recommend its use because they
were drawn up in the days of grades of purity of sugar and they
have not been updated. Some people claim it confers a better flavor
on the wine; which, like many things, is a matter of
personal preference.
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Cane
Sugar
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Cane
Sugar is refined from the juice of the sugar cane. Until recent
years it was the only source of pure sugar, but with the
improvement in refining techniques for beet sugar it forms only
about two-thirds of sugar consumed in the world. As long as the
packet says it contains pure sugar, it does not matter what name
it goes by or its parentage, since its effect on the wine is the
same whether the sugar is derived from cane or beet. See
Sucrose.
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Canned
Fruit
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Canned
Fruit A most useful and restful way of picking fruit. Provided
care is exercised in the choice, there is no reason why good wines
cannot be made. However, for dry wines it is essential to ensure
that no artificial sweetening agents have been used, for some of
these are non-fermentable and, despite no residual sugar on assay,
the wine will be sweet to the taste.
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Cap
of Pulp
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Cap
of Pulp At the start of a pulp fermentation the pulped fruit lies
at the bottom of the fermentation vessel but, within a few days,
as carbon dioxide production increases, the gas entrapped between
particles of fruit raises these to the surface to form the Cap of
Pulp. It is at this stage that infection is most likely to occur
and, to prevent this, in addition to ensuring maximum extraction
from the pulp, the cap should be broken up twice a day and the
must roused. It is useful to use a sinker to hold the cap below
the surface.
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Cap,
Crown
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Cap,
Crown The name given to the metal caps used for sealing bottles.
Mostly used for beer, they have in recent years come to be used
for the second stage of champagne making (bottle fermentation).
They have the advantage over cork of cost and of course the wine
cannot become corked. They require capper for their application,
but are much easier than champagne corks both to fit and remove.
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Capsules
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Capsules
Theoretically, these are used to seal the wine and its cork from
the air, to prevent the wine from becoming corked. However, some
capsules have holes pierced in them which destroys this
hypothesis. Whether the pierced ones were originally intended for
bottles expected to take years to come to maturity and therefore
might benefit from some air is not certain. However, it is certain
that they are decorative, thereby increasing the appeal of the
wine.
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Capsules,
Lead
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Capsules,
Lead Some commercial wines still use lead capsules on them. When
opening a bottle protected in this way it is important to remove
the whole capsule and not merely the top half-inch or so. This is
because lead is a toxic metal which will not gain entry to the
wine when used as a seal but, if not removed, may contaminate it.
As lead is an accumulative poison its effects are not immediately
seen.
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Capsules,
Plastic
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Capsules,
Plastic The amateur's posh capsule. Available in various colors,
they are shrink fitted and will, as well as enhancing the look of
the bottle, protect it from possible corking.
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Caramel
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Caramel
When sugar is heated about its melting point it turns from white
to brown as it loses its structure and becomes amorphous. This
brown substance is called caramel and is used for coloring and
flavoring wines, particularly the dessert and sweet types.
Delicate table wines should not have caramel added for its
powerful aroma and taste will obscure the intended flavor.
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Carbonates
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Carbonates
These are salts present in tap water and contribute to its pH and
hardness. Since carbonates precipitate on boiling care must be
taken with pH analysis if boiled water is to be used as there is
the possibility that the pH may be increased with its use and the
bacterial protection afforded by a low pH will be lost.
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Carbonation
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Carbonation
is achieved by forcing carbon dioxide into a bottle under pressure
(a dangerous technique for the amateur), or by encouraging a
bottle fermentation as in champagne making or as seen in the case
of a malo-lactic fermentation. In commercial "fizzy"
drinks, a pressure of 90 psi is not uncommon, but this is
dangerously high for the amateur who ought not to aim for more
than 50 psi.
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Carbonic
Acid
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Carbonic
Acid Carbon dioxide is very soluble in water and when it enters
solution it partially dissociates and forms a weak acid. This acid
is carbonic acid. It plays an important part in the buffering of
fermenting wines, but when fermentation is complete and the carbon
dioxide is lost, obviously so too is the carbonic acid. When
racking a young wine the presence of carbonic acid helps to
prevent oxidation by reacting with the oxygen absorbed.
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Carbonyl
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Carbonyl
Chemical compounds chiefly responsible for the bouquet of a wine.
They are all members of the aldehyde or ketone series.
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Carboxylase
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Carboxylase
One of the most important enzymes in alcohol production. It is
secreted by yeasts and its action is to promote the
decarboxylation (removal of carbon) of pyruvic acid to
acetaldehyde. In the process carbon dioxide is given off. Unlike
most of the reactions involved in alcohol production this one is
irreversible.
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Carboys
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Casein
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Casein
The principal protein of milk. In its pure form (although
expensive), it is an excellent fining agent. It is superior to
charcoal as a de-coloring agent since it does not absorb flavors.
The best way of using it is to dissolve the casein either in
strong ammonia and then boil until the ammonia is driven off, or
to dissolve it in sodium bicarbonate. It is common to prepare a
tannin-casein mixture of equal proportion for fining, as tannin
will combine with any excess protein to aid clearing.
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Cask
Sizes
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Cask
Sizes The most popular barrel sizes for the amateur are the 7, 11
and 22 gallon casks and with careful regulation of the time a wine
is allowed to remain in the wood, suffice for most people. The
range of sizes is from 1 to 45 gallons. For the amateur, space,
manageability and scale of production will dictate the size. For
most, sizes above 22 gallons are too unwieldy.
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Cask
Storage
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Cask
Storage Never keep a cask on its side without proper supports.
They should always be kept on their sides but supported at each
end in order to prevent warping, and should have stillages to
prevent rolling about, as well as bearing at least part of the
weight. If being kept empty, a cask should have a few pints of
stock sulphite in it and the cask upended. It should be turned
every few weeks to ensure total sterility.
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Cask
Topping up
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Cask
Topping up Due to the pores in the wood, there is an inevitable
loss of water and alcohol to the atmosphere. It is essential to
prevent the over-oxidation which will occur should the cask become
too empty, and therefore the cask must be topped up at regular
intervals with a wine of a similar type to that maturing.
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Catalyst
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Catalyst
Some chemical reactions progress so slowly that without help from
other compounds they would make almost none of the final compound.
Chemicals which speed up these reactions are called catalysts.
They act by forming intermediate products, which are then changed
into the final compound. The most peculiar characteristics of
catalysts is that they are not changed at the end of the reaction
that they catalyze. Thus, a small amount of a catalyst can speed
up a large amount of compounds reacting together. Reactions
needing catalysts are speeded up by increasing the temperature,
but if it is raised too much the reaction will slow down since
catalysts are often denatured by the heat as other proteins.
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Catechol
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Catechol
A tannin simple structure present in the grape, which contributes
most of the astringency to a finished wine.
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Cellar
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Cellar
A dry cellar is the ideal place for a wine store, since the
temperature can be kept constant while the sun is excluded.
Nowadays the cupboard under the stairs often has to double as a
wine cellar.
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Cellarcraft
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Cellarcraft
embraces the care of wine from the moment a must finishes
fermenting until it is served at table. This involves maturing,
bottling, corking, labeling, storage and, finally, serving the
wine.
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Champagne
Making
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Champagne
Making consists of several special steps after fermenting and
blending the dry base wine. The wine is sweetened and re-fermented
in the bottle and, when this is complete, the sediment is
collected in the neck by inverting the bottle over a period of
time and finally the loss of wine from disgorging is made good.
The wine is then matured and sold.
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Champagne
Yeast
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Champagne
Yeast A pure string of yeast which is unusual in that it can
ferment in the presence of a high concentration of carbon dioxide.
For successful sparkling winemaking this yeast is essential
especially for the bottle fermentation. See
Yeasts
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Champagne,
Sugar Additions
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Champagne,
Sugar Additions prior to re-fermenting must be carefully gauged to
obtain the maximum sparkle consistent with safety. The recommended
amounts are given in See
Appendix VIII.
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Chaptalization
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Chaptalization
The addition of sugar to commercial musts in a poor year when the
natural sugar of the grape is not sufficient to yield a high
enough alcohol level. The amount permitted is regulated by law in
France and the process takes its name from its inventor, M.
Chaptal. In virtually all amateur winemaking this is a normal
practice, as it is rare to find a fruit high enough in sugar to
give a satisfactory wine, except for the wine grape.
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Chlorine
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Chlorine
has two actions to the winemaker; one beneficial, the other
annoying. One the good side, it is in the form of bleach, a
powerful cleaning and sterilizing agent. It is, on the other hand,
an inhibitor of yeast, should the water supply have too high a
concentration. This problem can be overcome by the use of
bisulphite, 50 ppm, before inoculation with yeast.
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Chlorophyl
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Chlorophyl
the green pigment present in leaves responsible for plant
respiration. Yeasts are unusual plants in that they do not contain
this compound and therefore cannot utilize sunlight to obtain
energy as do all other plants.
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Cider
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Cider
A weakly alcoholic drink made from the fermented juice of apples.
Unlike the must prepared for apple wine production of the cider
must is high in tannin. The use of bitter apples is responsible
for this freshness and bite to be found in a good cider.
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Citral
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Citral
An example of a bouquet producing compound which is an aldehyde
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Clarification
and Pectin
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Clarification
and Pectin Most members of the plan kingdom contain pectin in
varying quantities and if, in a wine, pectin is not broken down,
the result will be a haze, due to its entering colloidal solution.
To obviate this possibility the routine use of pectin destroying
enzymes prior to fermentation is recommended; especially in the
case of pulp fermentation, to aid extraction of juice, color and
aromatic compounds.
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Clarification
and Refrigeration
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Clarification
and Refrigeration Many substances causing hazes are only partially
soluble and by lowering the temperature they are forced out of
solution, precipitate and leave a clear wine. A good example of
this is tartaric acid and its potassium salts. It is important to
rack the wine at as near the refrigeration temperature as possible
in order to prevent these substances re-entering solution.
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Clarification
and Sulphite
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Clarification
and Sulphite Apart from inhibiting the growth of a new yeast
colony from the remaining cells after racking, sulphite also aids
clearing by neutralizing the electrical charges one some colloidal
particles so that they precipitate out of suspension.
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Clarification
and Tannin
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Clarification
and Tannin has the ability to combine with protein to form
insoluble coagulates. Thus any suspected and diagnosed protein
haze requires treatment with tannin after trial finings.
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Clarity
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Clarity
The term used to describe the clearness, or limpidity, of a wine.
If there are no hazes, foreign bodies or deposits, and the wine is
absolutely translucent, then it is described as being "star
bright". The descendant stages are: clear, hazy and cloudy.
The last term being used for a wine which is obviously opaque
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Cloudiness
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Cloudiness
the term used to describe a wine which has an obvious degree of
opacity, usually when the opposite side of the container is not
clearly visible. See
Diagnosis of Faults, Appendix XI.?
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Co-Enzymes
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Co-Enzymes
are molecules usually smaller than their specific enzymes and are
essential for its action. Often they act as carriers of ions from
the substrate being acted on to an appropriate acceptor. Co-enzyme
I accepts hydrogen ions from pyruvic acid to become
dihydrocoenzyme I which, in order to fulfill the maxim that enzymes
are not used up, is then changed back to its original structure.
Having accepted hydrogen from a molecule of pyruvic acid, the
specific enzyme zymase can then perform its part in oxidizing
acetaldehyde to alcohol.
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Co-Factor
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Co-Factor
These have the same function as co-enzymes, but they are usually
metals in their various ionic forms, instead of being complex
organic molecules.
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Co-Ferment
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Co-Ferment
Another term for co-enzyme.
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Coagulation
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Coagulation
A phenomenon which occurs at the iso-electric point of a protein.
Proteins are peculiar in that they can form either acids or bases
depending on the pH of their solution. However, at the iso-electric
point, they can form neither and lose their colloidal state, and
fall out of solution or coagulate. Thus any change in the pH of
wine will increase the chances of protein coagulation. This is
likely to happen if two wines are blended. To prevent this
occurring after bottling, blended wines must be allowed to stand a
few months.
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